Nope. Possibly you might find a dual-mode card (IE, one that does both CGA *and* Hercules) that also has a composite port, but I'll bet you a shiny nickel that it won't do composite color accurate to the way that an original CGA card does. And it also won't be happy co-existing with a VGA card in CGA mode. MDA/Hercules *can* coexist with VGA, but there are asterisks there. Among other things it'll prevent you from using 16 bit RAM access on a VGA card so equipped because of obscure limitations in the ISA bus when mixing 8 and 16 bit cards.
A 486 really isn't a good platform if you really care about composite CGA games. Almost all the games where this is actually relevant are intended for XTs, and coincidentally (or not) also tend to be picky about CPU speed. Another thing you'll run into is a significant number of AT bus machines, especially faster ones, don't have a fully kosher 14.318Mhz clock signal on the ISA bus; it'll work well enough to drive monitor sync but, again, colorburst will be messed up. If this is a category of games you *really* want to see in their "full glory" I would suggest doing a separate machine for that. A 486 with a VGA card is fine for running most anything that's good on a 286 or later as long as you have a turbo switch, but XT games are kind of their own kettle of fish.