Greg,
No, I think you have the pins wrong when converting from a AT28C64.
Take a look at the pin out of the AT28C64:

Now to convert this to a 2732:

Pin 24 on the 2732 (VCC) is pin 26 on the AT28C64B. So when the 4K rom is selected on the motherboard you need to supply pin 28 on the AT28C64B with what the motherboard is supplying to what it thinks is pin 24 on a 2732. This is pin 26 on the AT28C64B. Since pin 26 is not connected to anything in the chip you are just running from the location of pin 24 of the 2732 to the real VCC of the AT28C64B.
Get it? It works fine and is what the converters do with a conversion board.
Of course, you cannot let the last address float but that is why I tie it low saying to use the lower memory 4K on the chip. But I think you already knew that. I am just including the description for completeness.
Takes two wires. On small and one long and you have a 4K ROM chip substitute.
Gary